Rory McIlroy will be sent out first in the singles matches as Europe attempt to regain the Ryder Cup on Sunday.
The Northern Irishman will face Justin Thomas in the opening match as USA captain Jim Furyk put his heavyweights out first.
Brooks Koepka, the defending US Open and USPGA champion, is second out against Paul Casey, with Webb Simpson, the 2012 US Open winner and May's Players champion, up against Justin Rose and Tiger Woods taking on Jon Rahm.
Europe's star players over the first two days, Tommy Fleetwood and Francesco Molinari, are fifth and ninth out respectively against Tony Finau and a desperately out-of-form Phil Mickelson.
The matches begin shortly after 11am.
(Europe names first)
1105: Rory McIlroy v Justin Thomas
1117: Paul Casey v Brooks Koepka
1129: Justin Rose v Webb Simpson
1141: Jon Rahm v Tiger Woods
1153: Tommy Fleetwood v Tony Finau
1205: Ian Poulter v Dustin Johnson
1217: Thorbjorn Olesen v Jordan Spieth
1229: Sergio Garcia v Rickie Fowler
1241: Francesco Molinari v Phil Mickelson
1253: Tyrrell Hatton v Patrick Reed
1305: Henrik Stenson v Bubba Watson
1317: Alex Noren v Bryson DeChambeau
Sunday #RyderCup match-ups pic.twitter.com/2bDE8EBxcZ— Ryder Cup Europe (@RyderCupEurope) September 29, 2018