The list of celebrities due to participate in Ant & Dec's televised golf tournament will include Samuel L Jackson, Sylvester Stallone, Andy Garcia, Boris Becker, Jodie Kidd and James Nesbitt.
The reality show will see two teams of celebrities from Europe and the US compete for the All-Star Cup.
Colin Montgomerie and Mark O'Meara will act as non-playing captains for Europe and the US respectively.
It has also been announced that Jamie Theakston and Kirsty Gallacher will host the event, which will be broadcast on Sky One between 27 and 29 August 27.
Chris Evans, Jodie Kidd, Boris Becker, Steve Redgrave and James Nesbitt have all been confirmed on the European team.
The US team will feature Samuel L Jackson, Sylvester Stallone, Andy Garcia, Chris O'Donnell and Haley Osment.
It has also been reported that Catherine Zeta Jones and her husband Michael Douglas may take part in the event.
Speaking about the event, Jodie Kidd said "I am naturally very competitive and I love golf."
Declan Donnelly, who created the show with fellow presenter Ant McPartlin, said: "We toyed with the idea of playing ourselves but we realised we would get really embarrassed by our level of expertise in the game."