Teachers across England and Wales are going on strike tomorrow after a decade of meagre earnings in a state-funded school system that has seen many take up second jobs or leave the profession altogether.

Hundreds of thousands of other workers including rail staff and civil servants will also walk out, making it the UK's biggest day of strikes in several decades when measured by the range of industries it will cover.

The National Education Union (NEU), which is organising the teachers' strikes, has asked for an above-inflation pay award funded fully by the government, so that schools can also cover other costs, from stationery to textbooks.

The strikes follow failed talks yesterday afternoon between Education Secretary Gillian Keegan and the general secretaries of unions representing teachers and headteachers, which had hoped to resolve a pay dispute which threatens disruption to more than 23,000 schools this week.

With inflation reaching double digits last year, teachers have seen a 23% real-terms pay cut since 2010, the union said.

The government, which has held unsuccessful talks with the NEU, has called its one-year, 5% pay award for teachers the highest "in a generation" and says it is investing £4 billion in schools over the next two years.

The NEU - which has planned seven days of strikes in total - has said that one in four teachers leave the profession within three years of qualification, impacting the education of children.

"I can't remember when we had enough staff to comfortably cover the school," said Sydney Heighington, 33, an assistant head teacher at an east London school.

"At the moment, you've got teachers just absolutely leaving in droves," he added, noting that some of his support staff colleagues had been forced to go to food banks because of rising bills and others had simply left to find work at supermarkets.

Mr Heighington, who teaches music, said more than a third of experienced full-time teachers and teaching staff had left his school last year. Only a fifth of those roles were filled - by trainee teachers.

Educators say schools having to pay teachers' salaries from their own pocket has left classrooms starved of money for textbooks, IT upgrades and school trips.

"You cut back on trips out, you don't go to the British Museum, you don't go and see stuff," said Steve Chalke, founder of the Oasis charity that runs more than 50 schools across Britain. "So subjects become a little bit more sterile, because you're not learning at every level."

Prime Minister Rishi Sunak wants to expand mathematics education in schools but the NEU said his plan fails to address teacher shortages, which mean one in eight maths lessons are taught by a teacher unqualified in the subject.