The Thrills are to play alongside REM at the Oxfam Make Trade Fair Concert in London next week.
Earlier this week it emerged that REM will headline the show, which will take place at the Hammersmith Apollo on Tuesday 14 September.
All profits go to Oxfam's Fair Trade campaign and pther performers include Razorlight, Jamelia and Minnie Driver.
The Thrills have already worked with REM guitarist Peter Buck who contributed guitar and mandolin to a track on their new album, 'Let’s Bottle Bohemia'.
To mark this week's release of 'Let's Bottle Bohemia', the band will appear at HMV Grafton Street store in Dublin this Friday, 10 September.